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Is It Safe to Use Oxidised Vitamin C in Skincare?
Beauty

Is It Safe to Use Oxidised Vitamin C in Skincare?

17 March 2025


Can I Still Use Oxidised Vitamin C?




Vitamin C as a skincare ingredient has a deep-rooted reputation for being highly effective, yet unstable powerhouse. Pushing all those outdated reports aside, vitamin C is certainly a favourite amongst skincare experts and fans alike.



You’ll find that the most common formula everyone tends to reach for are serums, this is because many find applying a serum enriched in vitamin C is the most effective way of benefiting from the skin reviving ingredient. If you are wanting to know more about vitamin C and how it can benefit the skin, check out our dedicated blog post about it over on the Beauty Insiders.




Now, let’s move on to exploring what happens and whether we can still use oxidised vitamin C. If you are sat there wondering how vitamin C can oxidise, here is a brief recap on the tell-tale signs your serum has oxidised.



Vitamin C, also known as L-Ascorbic Acid, is often formulated into serums that are light in consistency and colour, typically clear, or sometimes champagne in colour.




Once it oxidises, the serum will appear dark yellow, orange, and sometimes brown in colour.



You’ll find that once a serum is oxidised its potency is reduced up to 25%




If you find your serum or product to have an unusual odour it is clear sign you must stop using it completely as it will not benefit the skin in any way and could potentially cause irritation.



You can find out more about how to tell if your vitamin C has become oxidised in our blog post.




Can we use oxidised vitamin C serum?



Yes, you can, but only if it has turned slightly yellow. This is usually a sign of the oxidisation has started, but the formula is still potent enough to deliver its benefits to the skin. If however, it has a dark orange or brown colour to it, it’s best to avoid using it all together as it not only useless on the skin, it will also create a barrier on the surface of the skin that can interfere with other active ingredients and formulas absorbing effectively into the skin.




You will sometimes find there are different types of vitamin C found in various skincare products that vary in stability, the stable forms taking longer to oxidised and generally more potent. By this I mean some vitamin C types, such as L-ascorbic acid and sodium ascorbyl phosphate, both of which are water-soluble and are often formulated into products suited for those with an oily skin type that are prone to blemishes and acne flare-ups. If you have a dry skin type you may find other types of vitamin C that are richer in consistency and moisturising, such as ascorbly palmitate and tetrahexyldecyl ascorbate are better suited due to the fact they are lipid-soluble vitamin C types.



Is oxidised vitamin C harmful?




In a word, yes, oxidised vitamin C can become harmful to the skin. You’ll find that in some cases people suffer from unwanted skin irritation, but this isn’t the only problem. The effectiveness of your vitamin C serum is completely depleted. This means the skin no longer benefits from the benefits of the active. Benefits such as the antioxidants found in the formula that can ward off any exposure to free radicals, like pollution, central heating, harsh climates, and other environmental aggressors. With the vitamin C no longer containing the right potency it is unable to keep the lipid barrier of the skin strong and protected from further skin damage. This damage can result as fine lines, wrinkles, loss of elasticity, dark spots, and hyperpigmentation.



Finally, in some rare cases, applying oxidised vitamin C to the skin can lead to discolouration and yellowing of the skin which can take some time to subside.




Is vitamin C still good after oxidation?



Yes and no, as I have just explained, using an oxidised vitamin C product can often lead to some side effects if the formula has turned dark orange or brown. With it lacking in potency and the risk of it staining your skin it is said to avoid using vitamin C products once they have severely oxidised.




How do I know if my vitamin C has oxidised?



As I have already mentioned, the colour of your formula is a vital factor to keep an eye on. It is generally considered that if your serum begins to look yellow, orange, or brown, it’s time to chuck it out.




When using vitamin C serums, it is important to remember to store your product the correct way and use it in the most effective way too. This is something we will cover in the next section to share some tips with you about how to keep your vitamin C product fresher for longer.



How can you stop vitamin C from oxidising?




There are a few ways of preventing your vitamin C serum from oxidising too quickly and staying fresher for longer. So, here are our top tips of extending the shelf life of these potent powerhouse formulations.



Keep your vitamin C away from sunlight




Exposure to the sun can rapidly decrease the effectiveness and potency of the active ingredient. To keep it delivering the best results keep it in a cupboard or drawer. You must also not that all products containing vitamin C must come in an opaque or light blocking packaging.



Always secure your lid




This may sound silly to some, but it is very important you keep oxygen out of your serums. Any exposure to oxygen will make the vitamin C effectiveness deteriorate making it unable to perform. Misplacing a lid is something that is easily done, so better to be safe than sorry and double check before storing your vitamin C serum away.



Keep your products out of the bathroom

I understand how storing your skincare products in your bathroom cabinet makes sense. But it is possibly the worse place for your skincare products. The fluctuation in heat and being exposed to frequent humidity will alter the formulations and can interfere with how they work on the skin.

Remember about the products life cycle

If a vitamin C product is left unopened and stored in a drawer away from direct sunlight, it will last up to three years. Once it’s opened however, you’re looking at about 3 months until the potency begins to wear off. It is important to use your vitamin C serum as frequently as possible to reap the rewards and use up the formula whilst it is at its most potent state.

There you have a little insight into using oxidised vitamin C and how it will affect the skin. Don’t forget, if you have any further questions, you can come and find us in Instagram.

DQH Can I use salicylic acid first and then vitamin C? It’s easy to create a skincare routine, but knowing how to use it is another thing entirely. In most cases, if you’re not getting the desired skin results, it could be due to the layering of conflicting ingredients. So, is it possible that salicylic acid and vitamin C are such ingredients? Or are these active ingredients the duo that’s been missing from your skincare routine? If you want answers, stick around because today we are going to explain the benefits of salicylic acid and vitamin C and how they can be used in your daily life. What are the benefits of salicylic acid for skin? Salicylic acid is one of the most commonly used beta hydroxy acids and is favored by many people with oily, acne-prone skin. This acid is derived from willow bark, and unlike its water-soluble relatives (called alpha-hydroxy acids), salicylic acid is oil-soluble, which means it can penetrate deeper into the lower layers of the skin. Once it reaches the lower layers, it can help unclog pores of excess sebum, dirt, bacteria, debris, and impurities. This results in clearer skin tones and greater definition. Not only does salicylic acid benefit the underlying layers, but the outer surface of the skin benefits as well. When applied to the skin, salicylic acid removes the buildup of dead skin cells. This is accomplished by breaking the bonds that hold dead cells to the surface. Over time, this can cause the complexion to look dull and prone to acne, blackheads, and other blemishes. If you’d like to learn more about salicylic acid and how it can improve your skin, check out this dedicated blog post from a beauty insider. What are the benefits of vitamin C for skin? Vitamin C is considered one of the most powerful antioxidants, which means it is very effective at fighting free radicals and preventing them from causing further skin damage. Examples of free radicals include pollution, central heating, UV rays and harsh climate. They attack proteins, fats and cell membranes as soon as they come into contact with the skin, causing signs of premature aging such as fine lines and wrinkles as well as hyperpigmentation, flaky patches of skin and loss of elasticity. Many people usually prefer to use vitamin C in their morning routine as this ingredient gives the complexion a radiant glow. You’ll also find that vitamin C can target areas of hyperpigmentation, plumping the skin and reducing the appearance of fine lines and wrinkles. The thing about vitamin C is that there are a lot of outdated studies going back to the 1950s that describe vitamin C as an unstable skin component. Thanks to improvements in modern technology, this is no longer the case as all products now contain a stable form of vitamin C. Visit The Beauty Insider to learn more about vitamin C. So please check out our blog post. Can I use salicylic acid first and then vitamin C? Yes, you absolutely can. In fact, it’s thought that using salicylic acid before using vitamin C ensures it penetrates faster and works faster. This is an efficient way to utilize two power sources, and the reason has to do with pH. For example, the skin’s natural pH is about 4.7, making it slightly acidic. Salicylic acid and vitamin C are also both acidic, and you’ll find that vitamin C is absorbed quickly into the skin. Therefore, using salicylic acid beforehand can increase the acidity of the skin and allow vitamin C to penetrate into the skin faster. While this is considered an effective way to combine two powerful ingredients, you need to be aware of your skin type and how it reacts to certain active ingredients. Even people with perfect, normal skin can experience skin sensitivity and irritation. Therefore, always consult a doctor or dermatologist before using any new products on your skin. It’s also important to follow skin application rules. In this case, you need to use the product correctly to ensure you get the best results for your skin. If you’re not sure what I mean, the basic rule for skin is to start with the thinnest consistency and work your way up to the thickest consistency. This prevents a barrier from forming on the surface, preventing other active ingredients from penetrating the skin. Can I use salicylic acid at night and vitamin C in the morning? Yes, absolutely, this is considered the most effective way to get returns without any adverse side effects. This is because there is enough time between applications to ensure that the skin’s pH levels return to balance. You’ll also find that Vitamin C is rich in antioxidants and is perfect for use in the morning to ensure your skin is protected and looking its healthiest. Due to the small size of salicylic acid molecules, it is an acid that is able to reach the deepest parts of the skin. While this is effective at keeping skin clear, it also increases the risk of irritation and photosensitivity. Therefore, many people prefer to use powerful BHAs in their evening routine without exposure to UV rays, pollution, or harsh weather. Warning: If you avoid using sunscreen every day, none of these ingredients will do what your skin needs. The combination of chemical peels and powerful ingredients increases the risk of further damage to the skin’s surface. Use SPF 50 every day to keep your skin protected and your lipid barrier healthy, even on cloudy days, keeping your skin in top condition.
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